Synthesis and Hydrogen Sorption Properties of Carborane Based Metal−Organic Framework Materials
✍ Scribed by Farha, Omar K.; Spokoyny, Alexander M.; Mulfort, Karen L.; Hawthorne, M. Frederick; Mirkin, Chad A.; Hupp, Joseph T.
- Book ID
- 120560665
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 143 KB
- Volume
- 129
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
A new metal-organic framework [Fe 3 O(OOC-C 6 H 4 -COO) 3 (H 2 O) 3 ]Cl$(H 2 O) x was synthesized with a specific surface area of 2823 m 2 /g and a lattice parameter of 88.61 A ˚. Isostructural with MIL-101, this compound exhibits similar hydrogen adsorption properties, with maximum adsorption capac
## Abstract Postsynthetic modification is presented as a means to tune the hydrogen adsorption properties of a series of metal–organic frameworks (MOFs). IRMOF‐3 (isoreticular metal–organic framework), UMCM‐1‐NH~2~ (University of Michigan crystalline material), and DMOF‐1‐NH~2~ (DABCO metal–organic