A new layered perovskite compound, Ag,La,Ti,O,,, was synthesized by an ion-exchange reaction of M,La,Ti,O ," (M = Na,K) with a AgNO, molten salt. The crystal structure and the ionic conductivity of the ion-exchanged compound were investigated. The ionic conductivities attributed to the interlayer si
Synthesis and high ionic conductivity of new layered perovskite compounds, AgLaTa2O7 and AgCa2Ta3O10
โ Scribed by Kenji Toda; Takahito Suzuki; Mineo Sato
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 370 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0167-2738
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โฆ Synopsis
New layered perovskite compounds, AgLaTa,O, and AgCa,Ta,O ,,), have been synthesized by an ion-exchange reaction from parent compounds, RbLaTa,O, and RbCa,Ta,O,,.
The crystal structures of silver ion-exchanged compounds were determined by the Rietveld analysis for powder XRD patterns. These compounds, which are probably metastable, could only be obtained by the ion-exchange reaction. The relatively high ionic conductivities attributed to the interlayer silver ions were observed at high temperatures.
๐ SIMILAR VOLUMES
By solid state reaction two new layered perovskites have been synthesized related to the Ruddlesden-Popper family, K
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