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Synthesis and heterocyclization of 3-aryl-2-methyl-2-thiocyanatopropanamides

✍ Scribed by V. S. Baranovskii; R. V. Simchak; B. D. Grishchuk

Book ID
111459984
Publisher
Springer
Year
2009
Tongue
English
Weight
192 KB
Volume
79
Category
Article
ISSN
1070-3632

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## Abstract The synthesis of a series of methyl 3‐amino‐4‐aryl(or methyl)sulfonylthiophene‐2‐carboxylates by reaction of 3‐alkoxy‐2‐aryI(or methyl)sulfonylacrylonitriles with methyl thioglycolate in the presence of triethylamine is described. Hydrolysis/decarboxylation of the ester at the 2‐positio