The previously evaluated prototype, methyl 6-acetyl-2-[(4,6dimethoxypyrimidin-2-yl)oxy]benzoate, was modiÐed by the introduction of an oximino group. Further extensive synthetic modiÐcations were then made to the 6-alkyl moiety (R1), the ester moiety (R2), the alkoxyimino moiety (R3), the bridge-ato
Synthesis and herbicidal activity of new oxazinone herbicides with a long-lasting herbicidal activity against Echinochloa oryzicola
✍ Scribed by Masahiko Ikeguchi; Masahiko Sawaki; Hitoshi Nakayama; Hiroshi Kikugawa; Hiroshi Yoshii
- Book ID
- 105359537
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 164 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1526-498X
- DOI
- 10.1002/ps.900
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✦ Synopsis
Abstract
Chemical modification of the herbicide 1‐[2‐(benzothiazol‐2‐yl)isopropyl]‐4‐methyl‐3‐phenyl‐5__H__‐pyrrolin‐2‐one (MI‐2826) has revealed a new oxazinone herbicide, 3‐[2‐(7‐chlorobenzothiazol‐2‐yl)isopropyl]‐2,3‐dihydro‐6‐methyl‐5‐phenyl‐4__H__‐1,3‐oxazin‐4‐one (MI‐3069), for use in paddy fields. In comparing the phyototoxicity of the two herbicides to transplanted rice, the latter was superior to the former and kept the same predominant characteristic to control Echinochloa oryzicola Vasin for a long period of time owing to its long‐lasting residual effect. Copyright © 2004 Society of Chemical Industry
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