Synthesis and fungicidal activity of N -( p -sulfonylphenyl)- N 1 -carbamoylureas
β Scribed by Cremlyn, Richard J.; Ellam, Richard M.; Farouk, Sultan
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 216 KB
- Volume
- 52
- Category
- Article
- ISSN
- 1526-498X
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β¦ Synopsis
A series of 11 N-(p-sulfonylphenyl)-N1-carbamoylureas was prepared by reaction of 1,6-diphenyl-2,4-dioxohexahydro-s-triazine with chlorosulfonic acid and thionyl chloride. The resultant N-(p-chlorosulfonylphenyl)-N1-carbamoylurea was subsequently condensed with amines, butanol, hydrazine and sodium azide. The hydrazide was reacted with carbonyl compounds and the azide with trimethyl phosphite. The products were tested for in-vivo fungicidal activity against barley powdery mildew (Erysiphe graminis) ; the acetone hydrazone derivative showed the highest activity.
1998 SCI.
π SIMILAR VOLUMES
Four triphenyltin carboxylates formulated as o-Ph3SnOCOC6H4CH=N-Ar (Ar = C6H,; prepared and spectroscopically characterized. H4CH=NC6H, indicates that the tin atom, in each of the two molecules comprising the asymmetric unit, exists in a distorted tetrahedral geometry owing to an intramolecular acyl