Synthesis and functionalities of poly(N-vinylalkylamide). XII. Synthesis and thermosensitive property of poly(vinylamine) copolymer prepared from poly(N-vinylformamide-co-N-vinylisobutyramide)

✍ Scribed by Kazuya Yamamoto; Takeshi Serizawa; Yoichiro Muraoka; Mitsuru Akashi

• Publisher: John Wiley and Sons
• Year: 2000
• Tongue: English
• Weight: 168 KB
• Volume: 38
• Category: Article
• ISSN: 0887-624X
• DOI: 10.1002/1099-0518(20001001)38:19<3674::aid-pola210>3.0.co;2-n

✦ Synopsis

The differences in the polymerization abilities of N-vinylformamide (NVF) and N-vinylisobutyramide (NVIBA) and the synthesis of their copolymers were studied. The polymerization abilities were fairly good and quite similar to those of N-vinylacetamide (NVA), a monomer in the same class as N-vinylalkylamides. Since the monomer reactivity ratios were r 1 ϭ 1.08 and r 2 ϭ 0.92 (M 1 ϭ NVF, M 2 ϭ NVIBA), respectively, it is clear that the comonomers definitely were converted to random copolymers. The resulting copolymers poly(NVF-co-NVIBA) exhibited the cloud points sharply. The light transmittance profiles were the same as those for poly(NVIBA) although they increased from 39 °C for poly(NVIBA), with an increase in the corresponding hydrophilic NVF component. Our final objective was to produce a cloud point controlled polymer material with primary amino groups. To achieve this, we examined the hydrolysis of poly(NVF), poly(NVA), poly(NVIBA), and poly(NVF-co-NVIBA) to obtain poly(vinylamine) [poly(VAm)]. The hydrolytic cleavage of poly(NVF) and poly(NVA) was promoted by an increase in temperature. However, poly(NVIBA) was not cleaved appreciably. The hydrolysis of poly(NVF-co-NVIBA) was done under controlled conditions, and amino groups selectively were introduced to only one of two components of the copolymer. The cloud point of the hydrolyzed copolymer shifted to a higher temperature than that of the copolymer.