The enzyme-catalyzed synthesis of poly(p-ethylphenol) (PEP) was modified by copolymerization with polycarbonates through triphosgene at low temperature to form polycarbonate-co-poly(p-ethylphenol) (PC-co-PEP). FTIR, NMR, GPC, and thermal analysis verified the formation of PC-co-PEP. The copolymers h
Synthesis and film formation of polycarbonate-co- poly(p-ethylphenol)
β Scribed by J. Wang; K. E. Gonsalves
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 221 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0887-624X
No coin nor oath required. For personal study only.
β¦ Synopsis
The enzyme-catalyzed synthesis of poly(p-ethylphenol) (PEP) has received considerable interest in recent years. Nevertheless, the limited molecular weights restricts its application. In our preliminary research, PEP was modified by copolymerization with polycarbonates through both transesterification at high temperature, and triphosgene at low temperature to form polycarbonate-co-poly(p-ethylphenol) (PC-co-PEP). FTIR, NMR, GPC, and thermal analysis verified the formation of PC-co-PEP. The copolymers have an optical absorption in the UV range.
π SIMILAR VOLUMES
Copolymerization of acrylonitrile (AN) with p-trimethylsilylstyrene (TMSS) was carried out at 60Β°C in bulk and in solution in the presence of 2,2Πazobisisobutyronitrile (AIBN). The reactivity ratios of AN (M 1 ) and TMSS (M 2 ) were determined to be r 1 Ο 0.068 and r 2 Ο 0.309. The effects of the AI
Various poly(alkylene p,p-bibenzoate-co-adipate)s were prepared by melt polycondensation of dimethyl-p,p-bibenzoate, adipic acid, and an alkylene glycol. The copolyesters were characterized by inherent viscosity, FTIR, proton NMR, DSC, polarized microscopy, and X-ray diffraction. The polymer composi
A poly(p-methylstyrene-co-styrene)-block-poly(ethylene-co-butene)-blockpoly(p-methylstyrene-co-styrene) thermoplastic elastomer was prepared via anionic synthesis of poly(p-methylstyrene-co-styrene)-block-polybutadiene-block-poly(p-methylstyrene-co-styrene) followed by a hydrogenation of the polybut