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Synthesis and face- and stereo-selective cycloadditions of α-alkoxy cyclic nitrones

✍ Scribed by Sk.Asrof Ali; S.M.Azhar Hashmi; Mohammed I.M. Wazeer

Book ID
108386471
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
126 KB
Volume
39
Category
Article
ISSN
0040-4039

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✍ Pedro de March; Marta Figueredo; Josep Font; Antonio Salgado 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 630 KB

The 1,3-dipolar cycloaddition of cyclic nitrones to several "t-bromo ct,~unsaturated esters and lactones has been studied. All the reactions have shown high stereoselectivity, with a predominance of the endo or exo transition state for the trans or cis dipolarophiles, respectively.