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Synthesis and evaluation of hypothetical intermediates in the biosynthetic conversion of protoberberine to benzo[c]phenanthridine alkaloids. Evidence for oxidative carbon-nitrogen bond fission followed by intramolecular recyclization in cell cultures of Corydalis incisa

✍ Scribed by Iwasa, Kinuko; Kamigauchi, Miyoko; Takao, Narao; Cushman, Mark; Chen, Jer Kang; Wong, Wai Cheong; McKenzie, Ann

Book ID: 125856701
Publisher: American Chemical Society
Year: 1989
Tongue: English
Weight: 829 KB
Volume: 111
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00202a038

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Formation of benzo[c]phenanthridines by

Formation of benzo[c]phenanthridines by oxidative CN bond fission of protoberberines followed by intramolecular recyclization in cell cultures of corydalis incisa

✍ Kinuko Iwasa; Miyoko Kamigauchi; Narao Takao; Mark Cushman; Wai Cheong Wong; Jer 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 238 KB

Only 9 of the 6-hydroxy-13-methylprotoberberine N-metho salts 9 and 10 was trai?sformed by cell cultures of C. incisa into the Benzo[?Tphenanthridines, corynoline (1) and corymne (2).