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Synthesis and evaluation of a broad range of chiral sulfides for asymmetric sulfur ylide epoxidation of aldehydes

✍ Scribed by Aggarwal, Varinder K.; Angelaud, Rémy; Bihan, Dominique; Blackburn, Paul; Fieldhouse, Robin; Fonquerna, Silvia J.; Ford, Gair D.; Hynd, George; Jones, Elfyn; Jones, Ray V. H.; Jubault, Philippe; Palmer, Matthew J.; Ratcliffe, Paul D.; Adams, Harry

Book ID
121282767
Publisher
Royal Society of Chemistry
Year
2001
Weight
360 KB
Volume
20
Category
Article
ISSN
1472-7781

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Synthesis of novel C2-symmetrical chiral
Synthesis of novel C2-symmetrical chiral sulfides and their utility in asymmetric epoxidation of aldehydes
✍ Miyuki Ishizaki; Osamu Hoshino 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 92 KB 👁 2 views

## Abstract Novel C~2~‐symmetrical chiral sulfides were synthesized from (__R,R__)‐tartaric acid and their utility in the asymmetric epoxidation of aldehydes with benzyl bromide was examined. Among the sulfides used, silyl ether‐type sulfides were found to be superior to diol‐ and benzyl ether‐type