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Synthesis and Electrospray Ionization Mass Spectra of Amino Acid Thiophosphoramidates of Nucleoside

✍ Scribed by Zhi-Wei Miao; Hua Fu; Yi Chen; Jingd Chen; Chang-Mei Cheng; Yu-Fen Zhao

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
333 KB
Volume
19
Category
Article
ISSN
0256-7660

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## Abstract The fragmentation reactions of __N__‐monoalkyloxyphosphoryl amino acids (__N__‐MAP‐AAs) were studied by electrospray ionization tandem mass spectrometry (ESI‐MS). The sodiated cyclic acylphosphoramidates (CAPAs) were formed through a characteristic pentacoordinate phosphate participated