Neopentane-Based Tripodal CpL2 Ligands:
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Katrin Urtel; Axel Frick; Gottfried Huttner; Laszlo Zsolnai; Peter Kircher; Pete
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Article
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2000
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John Wiley and Sons
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English
⚖ 771 KB
Tripod ligands / Hindered rotation of vinylidene ligands / CpML 2 chelate ligands / Ruthenium / Carbenes / Carbene-type ligands / Cyclic voltammetry The tripodal ligand [CH 3 C(CH 2 C 5 H 4 )(CH 2 PPh 2 ) 2 ] -reacts C(OMe)Me (8), upon treatment with methanol. The vinylidene species 7 are deprotonat