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Synthesis and electrochemical studies of tetrathiafulvalene derivatives (TTFs) as redox active ligands

✍ Scribed by Abd El-Wareth A. O. Sarhan; Makoto Murakami; Taeko Izumi

Publisher: Journal of Heterocyclic Chemistry
Year: 2002
Tongue: English
Weight: 56 KB
Volume: 39
Category: Article
ISSN: 0022-152X
DOI: 10.1002/jhet.5570390413

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✦ Synopsis

Abstract

A simple route for synthesis of new tetrathiafulvalene dimethyl ester (TTF‐DME) is reported. The tetrathifulvalene dimethylester (TTF‐DME) has been prepared by introducing an ester coordination function as a bifunctional new donor. The redox behavior of the TTF‐DME was investigated in comparison to the well‐known dibenzotetrathiafulvene (DB‐TTF) by cyclic voltammetry. A two‐electron redox behavior was observed as a two waves.

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