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Synthesis and Electrochemical Properties of Homo- and Heterodimetallic Diethynylethene Bisphthalocyaninato Complexes

✍ Scribed by Maya, Eva M.; Vázquez, Purificación; Torres, Tomás; Gobbi, Luca; Diederich, François; Pyo, Soomi; Echegoyen, Luis


Book ID
125943674
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
137 KB
Volume
65
Category
Article
ISSN
0022-3263

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## Abstract Reaction of the triamidostannates(II) MeSi{SiMe~2~N(__p__‐tol)}~3~SnLi(OEt~2~) (1a) and MeSi{SiMe~2~N(3,5‐xyl)}~3~SnLi(OEt~2~) (1b) with 1/2 molar equiv. of [RhCl(diolefin)]~2~ (diolefin = COD, NBD) and phosphanes, phosphites or isonitriles (“L”) gave the square‐planar complexes [MeSi{S