Synthesis and Electrochemical Properties of a New 1D Organic–Inorganic Hybrid Compound Based on Keggin-Type Heteropolyanions and Isopolyanions Decorated by Transition Metal Fragments

Synthesis, property and crystal structur

Synthesis, property and crystal structure of a novel two-dimensional network organic–inorganic hybrid compound based on the neodymiumIII center and Keggin-type heteropolyanion of [α-BW12O40]5−

✍ Jingyang Niu; Junwei Zhao; Jingping Wang; Pengtao Ma 📂 Article 📅 2004 🏛 Elsevier Science 🌐 English ⚖ 279 KB

A novel two-dimensional infinite network organic -inorganic hybrid neodymium(III)-centered compound of formula (dmaH is obtained by the conventional selfassembly reaction of neodymium oxide, N,N-dimethylformamide and borotungstic acid (a-H 5 BW 12 O 40 •30H 2 O) in the mixed solvent of acetonitrile