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Synthesis and electrochemical behavior of a new series of macrocyclic complexes of iron produced by oxidative dehydrogenation and tautomerization

โœ Scribed by Dabrowiak, James C.; Lovecchio, Frank V.; Busch, Daryl H.


Book ID
127002465
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
371 KB
Volume
94
Category
Article
ISSN
0002-7863

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The synthesis of a new series of 14-and 16-membered hexaazamacrocyclic complexes has been achieved by the template condensation of ethylenediamine or 1,3propylenediamine with formaldehyde and acetamide in a 1:2:1 molar ratio in the presence of metal chlorides. Octahedral structural formulae for sele