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Synthesis and Electrochemical and EPR Studies of Spiked Butterfly Metal Clusters Containing an Fe3HgM Core (M = Mo, W, Fe, Mn, Co)

✍ Scribed by Reina, Roser; Rossell, Oriol; Seco, Miquel; Zquiak, Rachid; de Montauzon, Dominique


Book ID
126140401
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
691 KB
Volume
13
Category
Article
ISSN
0276-7333

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The anionic clusters [Fe 5 MN(CO) 14 Cp] 2-[M = Mo (1) or W (2)] were synthesized from [Fe 4 N(CO) 12 ] -and [MCp(CO) 3 ] - in refluxing acetonitrile. The clusters [Fe 3 M 3 N(CO) 18 ] 3-[M = Mo (3) or W (4)] were prepared by reaction of [Fe 4 N(CO) 12 ] - with [M 2 (CO) 10 ] 2-under the same condit