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Synthesis and electrochemical analysis of N-substituted pyrrole compounds

✍ Scribed by Koichi Kondo; Motonori Suwa; Atsushi Ozaki; Kiichi Takemoto


Publisher
Elsevier
Year
1992
Tongue
English
Weight
440 KB
Volume
333
Category
Article
ISSN
1572-6657

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The iodocyclization of a series of alkenyl-substituted p-enamino esters and ketones, followed by base-promoted dehydroiodination, led to the formation of the corresponding pyrrole or tetrahydroindole derivatives. In the absence of base, the iodo-I~-enamino esters 5 and 7 underwent spontaneous aromat

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## Abstract Cyclo[8]pyrrole was obtained efficiently when 3,3β€²,4,4′‐tetraethylbipyrrole was subjected to bulk electrolysis, with yields spanning a range from close to 0 % with tetra‐__n__‐butylammonium fluoride as the electrolyte, to almost 70 % when tetra‐__n__‐butylammonium hydrogensulfate was us