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Synthesis and DNA Binding of Novel Water-Soluble Cationic Methylcobalt Porphyrins

โœ Scribed by Trommel, Jenna S.; Marzilli, Luigi G.

Book ID
127021016
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
124 KB
Volume
40
Category
Article
ISSN
0020-1669

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Reactions of vinylchlorins and vinylporphyrins with N,N-dimethylmethyleneammonium iodide ("Eschenmoser's Reagent") gives Man&h adducts in which substitution (with CH2NMe2) has taken place on the terminal carbon of the vinyl group to yield a trans-3-(N,Ndimethylaminomethyl)prop-1 -enyl derivative. Un