## Abstract Poly(methyl methacrylate) (PMMA)/single‐walled carbon nanotube (SWNT) composites were synthesized by the grafting of PMMA onto the sidewalls of SWNTs via __in situ__ radical polymerization. The free‐radical initiators were covalently attached to the SWNTs by a well‐known esterification
Synthesis and Dispersion Characteristics of Multi-Walled Carbon Nanotube Composites with Poly(methyl methacrylate) Prepared by In-Situ Bulk Polymerization
✍ Scribed by Seung June Park; Min Seong Cho; Sung Taek Lim; Hyoung Jin Choi; Myung S. Jhon
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 158 KB
- Volume
- 24
- Category
- Article
- ISSN
- 1022-1336
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✦ Synopsis
Abstract
Multi‐walled carbon nanotubes (MWNT) purified by acidic solution were processed with PMMA via an in‐situ polymerization. Experimental evidences indicate the role of radical initiator (AIBN) and MWNT, showing increases of polymerization rate and MWNT diameter. Induced radicals on the MWNT by AIBN were found to trigger the grafting of PMMA. Moreover, the solvent cast film showed a better nanoscopic dispersion of MWNT and possibilities of CNT composites in engineering applications.
Fractured surface of multi‐walled carbon nanotube composite with PMMA prepared by in‐situ bulk polymerization.
magnified imageFractured surface of multi‐walled carbon nanotube composite with PMMA prepared by in‐situ bulk polymerization.
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