2-Trimethylsilylethyl-1,3-butadiene as a
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Akira Hosomi; Toshiyuki Masunari; Yoshinori Tominaga; Toshiharu Yanagi; Makoto H
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Article
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1990
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Elsevier Science
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French
β 262 KB
2-Trimethylsilylethyl-1,3-butadiene, readily prepared by the cross-coupling reaction of the Grignard reagent of 3-bromo-3-butenyltrimethylsilane with vinyl bromide catalyzed by a nickel-phosphine complex, works as a synthetic equivalent to 3-methylene-1,4-pentadiene (parent [3ldendralene) by the con