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Synthesis and dimerization of two cross-conjugated trienes: 3-methylene-1,4-pentadiene and 1,2,3-trimethylenecyclohexane

✍ Scribed by Trahanovsky, Walter S.; Koeplinger, Kenneth A.


Book ID
120319699
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
856 KB
Volume
57
Category
Article
ISSN
0022-3263

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2-Trimethylsilylethyl-1,3-butadiene as a
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2-Trimethylsilylethyl-1,3-butadiene, readily prepared by the cross-coupling reaction of the Grignard reagent of 3-bromo-3-butenyltrimethylsilane with vinyl bromide catalyzed by a nickel-phosphine complex, works as a synthetic equivalent to 3-methylene-1,4-pentadiene (parent [3ldendralene) by the con