## Abstract For Abstract see ChemInform Abstract in Full Text.
Synthesis and Diels—Alder Reactions of α-Fluoro- and α-Trifluoromethylacrylonitriles.
✍ Scribed by Valentine G. Nenajdenko; Vasiliy M. Muzalevskiy; Aleksey V. Shastin; Elizabeth S. Balenkova; Guenter Haufe
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 51 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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Synthesis and Diels-Alder Reactions of α,β-Unsaturated . gamma.-Sultone. -An improved synthesis of the unsaturated sultone (III) and its use in Diels-Alder reactions is described. The sultone cycloadducts can be ring-opened with various nucleophiles such as alcohols and amines.
Diels-Alder Reactions of α,β-Unsaturated Thioesters and α,β-Unsaturated Selenoesters. -The regio-and exo/endo-selectivity of Diels-Alder reactions of thio-and selenoesters (II) with dienes is investigated. In general, thermal reactions show only low selectivities as expected. The selectivity improv