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Synthesis and determination of absolute configuration of R-α-amino-benzylphenylphosphinic acid

✍ Scribed by Yu. P. Belov; G. B. Rakhnovich; V. A. Davankov; N. N. Godovikov; G. G. Aleksandrov; Yu. T. Struchkov

Book ID
112443055
Publisher
Springer
Year
1980
Tongue
English
Weight
585 KB
Volume
29
Category
Article
ISSN
1573-9171

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A new method proposed for the determinat
A new method proposed for the determination of absolute configurations of α-amino acids
✍ Edison Díaz Gómez; Helmut Duddeck 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 175 KB

## Abstract Enantiopure α‐amino acids were converted to 4‐substituted 2‐aryl‐ and 2‐alkyl‐5(4__H__)‐oxazolones under partial racemization. These nonracemic mixtures were dissolved in CDCl~3~, an equimolar amount of the chiral dirhodium complex $Rh^{\rm (II)}\_{2}$[(__R__)− (+)− MTPA]~4~ (MTPA‐H = M