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Synthesis and Crystallographic Characterisation of the Heterodimetallic Complex [(Dibenzo-18-crown-6)K(μ-Cl)3Ru(η6-p-cymene)]

✍ Scribed by Carsten A. Vock; Rosario Scopelliti; Paul J. Dyson

Book ID: 102170831
Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 100 KB
Volume: 2007
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.200700430

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✦ Synopsis

Abstract

The triple‐chlorido‐bridged heterodimetallic dinuclear complex [(dibenzo‐18‐crown‐6)K(μ‐Cl)~3~Ru(η^6^‐p‐cymene)] containing an (η^6^‐arene)Ru^II^ fragment and a Group 1 metal crown ether fragment was synthesized and characterized by spectroscopy and X‐ray crystallography. The solid‐state structure clearly reveals the presence of the triple‐chlorido‐bridged dinuclear complex, whereas NMR investigations in different deuteriated solvents reveal the presence of an essentially 1:1 mixture of 1 and starting materials, indicating the presence of a dynamic equilibrium. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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