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Synthesis and crystallographic analysis of a bicyclic core related to the esperamicin/calichemicin aglycones

✍ Scribed by Frank J. Schoenen; John A. Porco Jr.; Stuart L. Schreiber; Gregory D. VanDuyne; Jon Clardy

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 288 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)80649-3

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✦ Synopsis

The synthesis and crystallographic analysis of a bicyclic core related to the esperamicin/ calichemicin aglycones is reported.

A key reaction involves the skeletal rearrangement of a mesylate derived from a type II Diels-Alder cycloadduct.

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