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Synthesis and Crystal Structures of α-, β-Ba3(PS4)2 and Ba3(PSe4)2.

✍ Scribed by Stefan Joergens; Albrecht Mewis


Publisher
John Wiley and Sons
Year
2007
Weight
13 KB
Volume
38
Category
Article
ISSN
0931-7597

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Systematic studies on quaternary thio-and selenoborates containing heavier alkaline earth metal cations led to the two new isotypic crystalline phases Sr 4.2 Ba 2.8 (BS 3 ) 4 S and Ba 7 (BSe 3 ) 4 Se. Both compounds consist of trigonal-planar BQ 3 (Q = S, Se) units, isolated Q 2± anions and the corr