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Synthesis and crystal structures of the pseudobinary intermetallics IrIn2-xMgx with orthorhombic Mg2Cu structure and IrMg3-xInx with hexagonal Cu3P type

✍ Scribed by Viktor Hlukhyy; Rolf-Dieter Hoffmann; Rainer Pöttgen


Book ID
116573794
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
287 KB
Volume
12
Category
Article
ISSN
0966-9795

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A novel 1D coordination polymer, [Cu(picOH) 2 (BPE)] (IIa), and neutral [Cu(picOH) 2 (BPE) 2 ] (IIb) complexes, can be simultaneously isolated (structure II) when neutral [Cu(picOH) 2 ] (I) species are axially bridged by 1,2-bis(4-pyridyl)ethane (BPE) molecules. The compound has been characterised s