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Synthesis and Crystal Structure of δ-GeS2, the First Germanium Sulfide with an Expanded Framework Structure

✍ Scribed by Mark J. MacLachlan; Srebri Petrov; Robert L. Bedard; Ian Manners; Geoffrey A. Ozin

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 582 KB
Volume: 37
Category: Article
ISSN: 0044-8249
DOI: 10.1002/(sici)1521-3773(19980817)37:15<2075::aid-anie2075>3.0.co;2-l

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✦ Synopsis

The high-temperature high-pressure phase of GeS 2 (d) has been formed under very mild conditions by a rational assembly of adamantanoid [Ge 4 S 10 ] 4À clusters. An X-ray structure determination revealed two interpenetrating expanded cristobalite networks. Find out more on the following pages.

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