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Synthesis and crystal structure of zinc-vanadium complex [ZnII(LH3)(L)VIV][PF6]3 [LH3 = N,N',N''-tris(2S)-2-hydroxypropyl-1,4,7-triazacyclononane]: a chiral mixed-metal pendant-arm macrocyclic dimer containing nonvanadyl vanadium(IV)

✍ Scribed by Fallis, Ian; Farrugia, Louis J.; Macdonald, Norman M.; Peacock, Robert D.

Book ID: 126323895
Publisher: American Chemical Society
Year: 1993
Tongue: English
Weight: 238 KB
Volume: 32
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic00058a002

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Synthesis and structural and spectroscop

Synthesis and structural and spectroscopic studies of manganese complexes of pendant-arm macrocycles based on 1,4,7-triazacyclononane: crystal structures of the manganese(II) complex [MnLH3][MnCl4] and of the mixed-valence manganese(II)-manganese(IV) hydrogen-bridged dimer [MnLH3LMn][PF6]3 (LH3 = N,N',N''-tris[(2S)-2-hydroxypropyl]-1,4,7-triazacyclononane) and of the manganese(IV) monomer [MnL'][ClO4] (L'H3 = N,N',N''-tris(2-hydroxyethyl)-1,4,7-triazacyclononane)

✍ Belal, Arafa A.; Chaudhuri, Phalguni.; Fallis, Ian.; Farrugia, Louis J.; Hartung 📂 Article 📅 1991 🏛 American Chemical Society 🌐 English ⚖ 714 KB