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Synthesis and crystal structure of uranium(iv) complexes with calix[n]arenes (n = 4, 6 and 8): mononuclear, polynuclear and 1D polymeric species

✍ Scribed by Salmon, Lionel; Thu?ry, Pierre; Ephritikhine, Michel


Book ID
111937822
Publisher
Royal Society of Chemistry
Year
2006
Tongue
English
Weight
296 KB
Volume
30
Category
Article
ISSN
1477-9226

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Calixarenes with exo-hydroxy groups: Syn
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Ortho-tert-butylcalixarenes 3, 4 and 5 with exo-hydroxy groups were synthesised by tin tetrachloride-promoted condensation of 2,2"-dihydroxy-3,3"-di-tert-butyldiphenylmethane 6 with formaldehyde. While tH NMR analysis of compounds 3, 4 and 5 revealed a considerable annular flexibility in CDCI3 solut