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Synthesis and Crystal Structure of UO 2 Cl 2 (THF) 3 : A Simple Preparation of an Anhydrous Uranyl Reagent

✍ Scribed by Wilkerson, Marianne P.; Burns, Carol J.; Paine, Robert T.; Scott, Brian L.


Book ID
126781424
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
44 KB
Volume
38
Category
Article
ISSN
0020-1669

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πŸ“œ SIMILAR VOLUMES


Simple Preparations of the Anhydrous and
✍ JeanΒ Claude Berthet; Monique Lance; Martine Nierlich; Michel Ephritikhine πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 297 KB

Treatment of UO 3 with pure triflic acid TfOH at 110 Β°C or with boiling triflic anhydride TfOTf afforded [UO 2 (OTf) 2 ] (1) in high yields. The latter was also prepared by the reaction of UO 3 with TfOH in water, or by dehydration of [UO 2 (OTf) 2 (H 2 O) n ] in boiling TfOTf. Anhydrous [Ce(OTf) 4