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Synthesis and crystal structure of the iron(II)–iron(III) complex [FeL][FeCl4]Cl [L = 1,4,7-tris(pyrazol-3-ylmethyl)-1,4,7-triazacyclononane]

✍ Scribed by Di Vaira, Massimo; Mani, Fabrizio; Stoppioni, Piero


Book ID
120333023
Publisher
The Royal Society of Chemistry
Year
1997
Tongue
English
Weight
400 KB
Volume
8
Category
Article
ISSN
1472-7773

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The complexation of iron(iii) chloride with 1,4,7-tris[3,4-bis(decyloxy)benzyl]-1,4,7-triazacyclononane leads to a liquid crystalline product, which forms a second mesophase after thermal treatment at around 70 8C above the first clearing temperature. Polarizing microscopy, DSC, and UV observations