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Synthesis and crystal structure of the 16 e− cationic tungsten(IV) complex [WCp*(4,4′-Me2bipy)Cl2]+BPh4− †

✍ Scribed by Cremer, Christian; Burger, Peter


Book ID
121807319
Publisher
The Royal Society of Chemistry
Year
1999
Tongue
English
Weight
210 KB
Volume
12
Category
Article
ISSN
1472-7773

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Novel tetrameric rhenium(V) complexes have been prepared from [ReNCl 2 (PPh 3 ) 2 ] and [ReN(PMe 2 Ph) (S 2 CNEt) 2 ], respectively. [ReNCl 2 (PPh 3 ) 2 ] reacts with 1.5 equivalents of KS 2 CNEt 2 in methanol to yield the unusual dark red species [{cyclo-ReN} 4 (S 2 CNEt 2 . The crystal structure