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Synthesis and crystal structure of some phosphite, thiophosphite, and amidophosphite copper(I) halide complexes

✍ Scribed by Lidiya I. Kursheva; Olga N. Kataeva; Dmitry B. Krivolapov; Aidar T. Gubaidullin; Elvira S. Batyeva; Oleg G. Sinyashin

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 282 KB
Volume: 19
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.20459

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✦ Synopsis

Abstract

Some Cu(I) halides complexes based on P(III) acid esters,{[(RE)~3~PCuBr] (where E = O, N, S); R = n‐Pr, i‐Pr, Et~2~N} were obtained and characterized using IR, ^31^P NMR spectroscopy, and single crystal X‐ray diffraction. The comparative structural characteristics of complexes with various donor atoms (E = O, N, S) are analyzed. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:483–489, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20459

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