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Synthesis and Crystal Structure of NZP-Type Thorium−Zirconium Phosphate
✍ Scribed by Orlova, Albina I.; Volgutov, Valeriy Yu.; Castro, Germán R.; García-Granda, Santiago; Khainakov, Sergei A.; García, José R.
- Book ID
- 111869109
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 694 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0020-1669
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📜 SIMILAR VOLUMES
A series of zirconium phosphate fluorides were synthesized and structurally characterized using different amines as templates. The compounds have the general formulas [amH n ] 1/n [Zr 2 (HPO 4 )(PO 4 ) 2 F] • H 2 O (1, am ؍ ethylenediamine, n ؍ 2; 2. am ؍ N-methylethylenediamine, n ؍ 2; 3, a
Three new zirconium phosphate 6uorides, [amH 2 ] 0.5 [Zr 2 (PO 4 )(HPO 4 ) 2 F 2 ] ' 0.5H 2 O (1), [amH 2 ] 1.5 [Zr 3 (PO 4 ) 3 F 6 ] ' 1.5H 2 O (2) (am ؍ trans-1,4-diaminocyclohexane for 1 and 2), and [amH 2 ] 0.5 [Zr 3 (PO 4 ) 3 (HPO 4 )F 2 ] ' 1.5H 2 O (am ؍ 2,2dimethyl-1,3-diaminopropane) (3