Synthesis, crystal and electronic struct
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François Cheviré; Chinmoy Ranjan; Francis J. DiSalvo
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Article
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2009
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Elsevier Science
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English
⚖ 1016 KB
The rare earth-transition metal ternary nitride La 3 Cr 2 N 6 was synthesized from the elements and an excess of sodium and gallium at 900 • C in a sealed niobium tube. This compound crystallizes in the tetragonal space group I4/mmm (No. 139) with a = 3.8525(5) Å and c = 20.508(4) Å. It is isostruct