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Synthesis and crystal structure of [CrCl3(dmpe)]2(μ-dmpe)·2(CH2Cl2): A diphosphine ligand bridging two isolated Cr(III) centers

✍ Scribed by Atta M. Arif; Richard A. Jones; John G. Hefner


Book ID
105107456
Publisher
Springer
Year
1986
Tongue
English
Weight
305 KB
Volume
16
Category
Article
ISSN
1572-8854

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## Elimination of chloride from Cp\*Rh(L-PheO)Cl with AgBF, leads to the trinuclear complex [Cp\*Rh(p-L-Phe0)],3+(BF4-)3 (Z), in which the amino acidate acts both as an (N, 0)-chelating and as a carboxylate bridging ligand according to the X-ray structural determination. Trimerization of [Cp\*Rh(P