## Abstract The Mannich aminomethylation reaction of aromatic thiols has been used to produce diazaβ18βcrownβ6 ligands containing thiolβderived side arms. Thiophenols were attached to the azacrown through NβCH~2~βS linkages even in the presence of hydroxy or acetamido groups. Heteroaromatic thiols
Synthesis and crystal structure of copper complex of bis(p-chlorophenol)-containing diaza-18-crown-6 ligand
β Scribed by Shu-Lan Ma; Wen-Xiang Zhu; Chuan-Min Qi; Qian-Ling Guo; Jing Zhang; Ying-Chun Liu; Miao-Qiong Xu
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 153 KB
- Volume
- 703
- Category
- Article
- ISSN
- 0022-2860
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A new 7,16-bis(quinolin-8-ylmethyl)-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane ligand, L, has been prepared and its crystal structure reported. In addition, the structure of the protonated ligand H 2 L has been determined. H 2 L is of interest because of interatomic interactions between the ligand