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Synthesis and crystal structure of [(CO)6Fe2(μ-SeCH3)2]

✍ Scribed by Pradeep Mathur; Rajiv Trivedi; Munkir Hossain; S.S. Tavale; Vadavati G. Puranik

Book ID
107812691
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
370 KB
Volume
491
Category
Article
ISSN
0022-328X

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The reaction of Na 2 [Fe(CO) 4 ] with Br 2 CF 2 in npentane generates a mixture of the compounds (CO) 3 Fe(l-CO) 3±n (l-CF 2 ) n Fe(CO) 3 (2, n = 2; 3, n = 1) in low yields with 3 as the main product. 3 is obtained free from 2 by reacting Br 2 CF 2 with Na 2 [Fe 2 (CO) 8 ]. The non-isolable monomeri