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Synthesis and crystal structure of Ca9Cu1.5(PO4)7 and reinvestigation of Ca9.5Cu(PO4)7

โœ Scribed by A.A. Belik; O.V. Yanov; B.I. Lazoryak

Book ID
114065851
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
273 KB
Volume
36
Category
Article
ISSN
0025-5408

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Synthesis and X-ray Powder Diffraction S
Synthesis and X-ray Powder Diffraction Study of New Phosphates in the Cu3(PO4)2โ€“Sr3(PO4)2 System: Sr1.9Cu4.1(PO4)4, Sr3Cu3(PO4)4, Sr2Cu(PO4)2, and Sr9.1Cu1.4(PO4)7
โœ A.A. Belik; A.P. Malakho; B.I. Lazoryak; S.S. Khasanov ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 742 KB

New phosphates, Sr1.9Cu4.1(PO4)4, Sr2Cu(PO4)2, and Sr9.1Cu1.4(PO4)7, were found in the Cu3(PO4)2+Sr3(PO4)2 system at 9003C under air. Sr1.9Cu4.1(PO4)4 crystallizes in an orthorhombic system with a โ€ซุโ€ฌ 15.3695(7) A > , b โ€ซุโ€ฌ 10.3652(4) A > , and c โ€ซุโ€ฌ 7.9425(4) A > . Crystal structures of Sr9.1Cu1.4(