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Synthesis and Crystal Structure of BaZn(CO3)F2; Revision of the Structure of BaMn(CO3)F2.

✍ Scribed by A. Ben Ali; V. Maisonneuve; L. S. Smiri; M. Leblanc

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
33
Category
Article
ISSN
0931-7597

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AuF 3 , Au(SbF 6 ) 2 , or [Au(SbF 6 ) 2 Β΄Au(AuF 4 ) 2 ] react with AsF 3 in HF/SbF 5 under formation of F 3 AsΒ±Au + SbF 6 Β± . This is stable to about 0 Β°C. The crystal structure reveals strong cationic-anionic interactions through one fluorine atom so that a description as F 3 AsΒ±AuΒ±F. . . SbF 5 is