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Synthesis and crystal structure of a tetranuclear manganese(IV) cluster [L4Mn4O6](ClO4)4·2H2O (L = 1,4,7-triazacyclononane)

✍ Scribed by Lei Zhang; Shiping Yan; Chunhui Li; Daizheng Liao; Zonghui Jiang; Peng Cheng; Genglin Wang; Linhong Weng; Xuebing Leng


Book ID
110275176
Publisher
Springer
Year
2000
Tongue
English
Weight
68 KB
Volume
30
Category
Article
ISSN
1572-8854

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Synthesis of a Tetranuclear Manganese(IV
✍ Prof. Dr. Karl Wieghardt; Ursula Bossek; Dr. Walter Gebert 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 248 KB 👁 1 views

overall alternating arrangement of ligands (R,R,S,S), along the c-crystal axis results[41. Thus, mixing the pure quasienantiomers (1s)-1 and (1R)-3 produces the quasiracemate as a highly ordered columnar structure with a onedimensional (Rh,Rh,Ir,Ir)chain of central atoms. The Rh-Rh, Ir-IF, and Rh-Ir