Synthesis and crystal structure of a stable S-nitrosothiol bearing a novel steric protection group and of the corresponding S-nitrothiol

✍ Scribed by Kei Goto; Yoko Hino; Takayuki Kawashima*; Masahiro Kaminaga; Emiko Yano; Gaku Yamamoto; Nozomi Takagi; Shigeru Nagase

• Book ID: 104211037
• Publisher: Elsevier Science
• Year: 2000
• Tongue: French
• Weight: 125 KB
• Volume: 41
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)01487-8

✦ Synopsis

The molecular structure of a stable S-nitrosothiol bearing a novel trityl-type steric protection group was established by X-ray crystallographic analysis together with that of the corresponding S-nitrothiol. It was found that the S-nitrosothiol exists as a mixture of the syn and anti isomers with respect to the C S N O linkage in the crystalline state, in agreement with the theoretical calculation on Ph 3 CSNO.