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Synthesis and crystal structure of a novel 2-D hybrid compound [(PbBr2)2(μ-Pyz)]n (Pyz=pyrazine)

✍ Scribed by Yu-Jun Shi; Xue-Tai Chen; Chen-Xin Cai; Yong Zhang; Ziling Xue; Xiao-Zeng You; Shi-Ming Peng; Gene-Hsiang Lee

Book ID
108495939
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
307 KB
Volume
5
Category
Article
ISSN
1387-7003

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📜 SIMILAR VOLUMES

Synthesis, Structural Isomerism, and Mag
Synthesis, Structural Isomerism, and Magnetism of Extended Framework Compounds of Type [Cu (dca)2(pyz)]n, Where dca=Dicyanamide (N(CN)−2) and pyz=Pyrazine
✍ Paul Jensen; Stuart R. Batten; Gary D. Fallon; David C.R. Hockless; Boujemaa Mou 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 282 KB

Two structural isomers of the dicyanamide (dca, N(CN) ؊ 2 ) complex [Cu(dca) 2 (pyz)] n (pyz ‫؍‬ pyrazine) were prepared from aqueous solution and crystals were grown by slow di4usion and gel techniques. Crystal data: -[Cu(dca) 2 (pyz)] n , CuC 8 H 4 N 8 , monoclinic, Pn, Z ‫؍‬ 16, a ‫؍‬ 24.2549(7)

Synthesis, Structural Isomerism, and Mag
Synthesis, Structural Isomerism, and Magnetism of the Coordination Polymers [M(dca)2pyz], M=Mn, Fe, Co, Ni and Zn, dca=Dicyanamide (N(CN) −2), and pyz=Pyrazine
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The coordination polymers [M(dca) 2 pyz] (M ‫؍‬ Mn, Fe, Co, Ni, Zn) have been synthesized and characterized by singlecrystal and powder X-ray di4raction. Two isomers have been observed. The compounds contain two interpenetrating 3D -Po related networks. Bidentate dca ligands bridge the metal atoms t