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Synthesis and crystal structure of a new oxynitride, Ba3ZnN2O

✍ Scribed by Hisanori Yamane; Francis J DiSalvo


Book ID
116160897
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
333 KB
Volume
234
Category
Article
ISSN
0925-8388

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A new niobium oxynitride Nb 2 N 0.88 O 0.12 has been synthesized by reducing Nb 2 O 5 in a stream of H 2 gas containing 0.07% N 2 at 10803C for 5 weeks. The compound crystallizes in a hexagonal system with space group P3 1m, and Z ‫؍‬ 3. The lattice parameters are a ‫؍‬ 5.2916$0.0001 A s and c ‫؍‬ 4

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Single crystals of \(\mathrm{Ba}_{3} \mathrm{Nb}_{2} \mathrm{O}_{2} \mathrm{~F}_{12} \cdot 2 \mathrm{H}_{2} \mathrm{O}\) were grown by hydrothermal synthesis in \(\mathrm{HF}\) aqueous solutions. The structure is established from single crystal X-ray diffraction data: S.G. \(C m c 2_{1}, Z=4, a=22.6