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Synthesis and crystal structure of a new dinuclear manganese(II) complex of a macrocyclic ligand with multi-ligating pendant-arms

✍ Scribed by Yuanxiang Luo; Jiangrun Zhang; Lude Lu; Ming Qian; Xin Wang; Xujie Yang; Fangfang Jian


Book ID
110339991
Publisher
Springer
Year
2002
Tongue
English
Weight
109 KB
Volume
27
Category
Article
ISSN
0340-4285

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✍ Ming Qian; Shaohua Gou; Zhi Yu; Huangxian Ju; Yan Xu; Chunying Duan; Xiaozeng Yo πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 142 KB

A dinuclear manganese macrocyclic complex with functional pendant arms, [Mn 2 (II)HL 2 ](ClO 4 ), has been prepared by the cyclocondensation of sodium 2,6-diformyl-4-methylphenolate with N,N-bis(2-aminoethyl)-N-(2-hydroxybenzyl)amine and subsequent transmetallation of Mn(II)(ClO 4 ) 2 . In the molec

Pendant-armed Unsymmetrical Aza-macrocyc
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## Abstract Two unsymmetrical tetradentate __aza__‐macrocycles with side arms attached to the N~sp~^3^ atoms, L^1^ and L^2^, as well as their complexes with different metal cations were synthesized and characterized by EA, UV, IR, ^1^H NMR and MS spectra. Both the two ligands can efficiently transp