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Synthesis and crystal structure of a four-coordinate aryloxo samarium complex [Sm(OAr)3(THF)](THF) (OAr = 2.6-ditertbutyl-4-methylphenoxo)

✍ Scribed by Guizhong Qi; Yonghua Lin; Jingyu Hu; Qi Shen


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
177 KB
Volume
14
Category
Article
ISSN
0277-5387

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Reaction of [Yb(OAr) 2 (THF) 3 ] (OAr = OC 6 H 2 -2,6-tBu 2 -4-R; R = H, Me, tBu) with perfluorodecalin in THF at room temperature results in C-F activation and formation of the first heteroleptic aryloxofluorolanthanoid complexes, [Yb-(OAr) 2 F(THF)] 2 . Oxidation of bis(cyclopentadienyl)ytterbium(