Syntheses and Structures of Bis(aryloxo)
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GlenΒ B. Deacon; Gerd Meyer; Dirk Stellfeldt
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Article
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2000
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John Wiley and Sons
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English
β 546 KB
Reaction of [Yb(OAr) 2 (THF) 3 ] (OAr = OC 6 H 2 -2,6-tBu 2 -4-R; R = H, Me, tBu) with perfluorodecalin in THF at room temperature results in C-F activation and formation of the first heteroleptic aryloxofluorolanthanoid complexes, [Yb-(OAr) 2 F(THF)] 2 . Oxidation of bis(cyclopentadienyl)ytterbium(