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Synthesis and Crystal Structure of a “FeBi” Cluster Compound with Noncovalent Low-Valent Bi···π Arene Interactions

✍ Scribed by Monakhov, Kirill Yu.; Gourlaouen, Christophe; Zessin, Thomas; Linti, Gerald


Book ID
120368686
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
582 KB
Volume
52
Category
Article
ISSN
0020-1669

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The reaction of PhN 3 (H)C 6 H 4 N 3 (H)Ph with Hg(NO 3 ) 2 in THF in the presence of triethylamine yields {Hg[PhN 3 C 6 H 4 N 3 (H)Ph](NO 3 )} as a yellow powder that can be recrystallized from THF/acetone. The crystals belong to the monoclinic system, space group P2 1 with the cell dimensions a ϭ