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Synthesis and Crystal Structure of a 1D Silver(I) Complex {[Ag (L)(CH3CN)](ClO4)}n[L

✍ Scribed by Qian Gao; Ya-Bo Xie; Sha Chen; Dao Wang

Publisher: Springer
Year: 2007
Tongue: English
Weight: 231 KB
Volume: 37
Category: Article
ISSN: 1572-8854
DOI: 10.1007/s10870-007-9249-y

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## Abstract The first argentate salt of carborane anion, [{(CH~3~CN)~4~Ag~3~}{Ag(CB~11~I~5~Br~6~)~2~}]~__n__~, was prepared from K~2~[CB~11~I~5~Br~6~] and AgNO~3~ followed by recrystallization from acetonitrile. Single‐crystal X‐ray analyses indicate that the CB~11~I~5~Br~6~^2−^ dianion has a signi