✦ LIBER ✦

Synthesis and crystal structure of 5,10,15,20-tetrakis(3,5-dinitrophenyl)porphyrin

✍ Scribed by P. Bhyrappa; K. S. Suslick

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 452 KB
Volume: 02
Category: Article
ISSN: 1088-4246
DOI: 10.1002/(sici)1099-1409(199807/10)2:4/5<391::aid-jpp95>3.0.co;2-u

No coin nor oath required. For personal study only.

✦ Synopsis

The synthesis, characterization and crystal structure of the octanitro-substituted porphyrin 5,10,15,20-tetrakis(3,5-dinitrophenyl)porphyrin, H 2 T(3,5-DNP)P, are described. The solid state structure has two porphyrins in the unit cell with eight pyridine solvates and is made up from columnar arrays of the porphyrins. X-ray crystal structure data: monoclinic, space group P1 2 1 /n1, a = 14.9996( ) A ˚, b = 8.2489(5) A ˚, c = 24.818(2) A ˚, a = 90°, b = 104.172(1) °, g = 90°, V = 2977.3(3) A ˚3, d calc = 1.440 g m À3 , Z = 2. # 1998 John Wiley & Sons, Ltd.

📜 SIMILAR VOLUMES

Synthesis, reactivity and structural che

Synthesis, reactivity and structural chemistry of 5,10,15,20-tetraalkylporphyrins

✍ MATHIAS O. SENGE; INES BISCHOFF; NORA Y. NELSON; KEVIN M. SMITH 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 223 KB

The synthesis, reactivity and full characterization of a series of meso-tetraalkyl porphyrins and metalloporphyrins with R n-butyl (6), 2-methyl-propyl (7), isopropyl (8), l-ethyl-propyl (10) and tertbutyl (11) groups are reported. Derivatives of the last of these show considerably bathochromically

Crystal Structure and Molecular Structur

Crystal Structure and Molecular Structure of 3,5,8,10-Tetramethylaceheptylene

✍ Dipl.-Ing. E. Carstensen-Oeser; Priv.-Doz. Dr. G. Habermehl 📂 Article 📅 1968 🏛 John Wiley and Sons 🌐 English ⚖ 115 KB 👁 2 views

Synthesis, molecular and crystal structu

Synthesis, molecular and crystal structure, and properties of 10-propylthio-5,10-dihydrophenarsazine

✍ Il'yas S. Nizamov; Tat'yana P. Sorokina; Alexey V. Matseevskii; Dmitry B. Krivol 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 116 KB 👁 2 views

Resonance Raman Studies of Mono- and Dif

Resonance Raman Studies of Mono- and Difluoro-5,10,15,20-tetrakis(pentafluorophenyl)porphyriniron(III)

✍ Insook Rhee Paeng; Hakhyun Nam; Sang Woo Lee; Ki-Jung Paeng 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 391 KB

Resonance Raman (RR) spectra of 5,10,15,20-tetrakis(pentaÑuorophenyl)porphyriniron(III) diÑuoride, which was formed by the reaction between Fe(TPFPP)Cl and tetrabutylammonium Ñuoride [ Fe(TPFPP)F 2 ] -, in various non-aqueous solvents, were obtained with the 406.7 nm (Kr' laser) or 441.6 nm (TBA'F-A

Osmium Complexes of the 5,10,15,20-Tetra

Osmium Complexes of the 5,10,15,20-Tetrakis(4-phosphonomethylphenyl)porphyrin Anion, A New Water-Soluble Tetraphenylporphyrinate System

✍ Johann W. Buchler; Joachim R. Simon 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 322 KB

Folding and Hydrodynamic Forces in J-Agg

Folding and Hydrodynamic Forces in J-Aggregates of 5-Phenyl-10,15,20-tris(4-sulfophenyl)porphyrin

✍ Carlos Escudero; Joaquim Crusats; Ismael Díez-Pérez; Zoubir El-Hachemi; Josep M. 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 211 KB